Q.

Rates of reaction of zero, first & second order reactions having same magnitude of rate constants are γ1,γ2,γ3 respectively. The order of γ1,γ2,γ3if the concentration of reactant is lesser than unity.

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a

cannot be predicted

b

γ1<γ2<γ3

c

γ1=γ2=γ3

d

γ1>γ2>γ3

answer is A.

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Detailed Solution

r1=k1[A]0;r2=k2[A]1;r3=k3[A]2

since concentration [A] < 1

r1 > r2 > r3

let concentration [A] = 0.1 in each case

r1=k1[0.1]0;r2=k2[0.1]1;r3=k3[0.1]2

r1=k1;r2=k210;r3=k3100

since magnitude is same 

r1:r2:r3=k1:k110:k1100

r1 > r2 > r3

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