(Rates of reaction of zero first, second order reactions having same magnitude of rate constants are γ1,γ2,γ3 respectively). Relate γ1,γ2,γ3 if the concentration of reactant is greater than unity and same for all reactions

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(Rates of reaction of zero first, second order reactions having same magnitude of rate constants are $γ_{1}, γ_{2}, γ_{3}$ respectively). Relate $γ_{1}, γ_{2}, γ_{3}$ if the concentration of reactant is greater than unity and same for all reactions

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cannot be predicted

$γ_{1} = γ_{2} = γ_{3}$

$γ_{1} > γ_{2} > γ_{3}$

$γ_{1} < γ_{2} < γ_{3}$

answer is B.

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Detailed Solution

order of reaction	rate law
Zero	$γ_{1}$ = $K_{0} {[A]}^{0}$
first	$γ_{2}$ = $K_{1} {[A]}^{1}$
second	$γ_{3}$ = ${[A]}^{2}$

since magnitude of rate constant is same for all and concentration of reactant is greater than 1 and equal for all reactions from the rate law equation $γ_{1}$ < $γ_{2}$ < $γ_{3}$

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