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(Rates of reaction of zero first, second order reactions having same magnitude of rate constants are $γ_{1}, γ_{2}, γ_{3}$ respectively). Relate $γ_{1}, γ_{2}, γ_{3}$ if the concentration of reactant is greater than unity and same for all reactions

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$γ_{1} > γ_{2} > γ_{3}$

$γ_{1} < γ_{2} < γ_{3}$

$γ_{1} = γ_{2} = γ_{3}$

cannot be predicted

answer is B.

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Detailed Solution

order of reaction	rate law
Zero	$γ_{1}$ = $K_{0} {[A]}^{0}$
first	$γ_{2}$ = $K_{1} {[A]}^{1}$
second	$γ_{3}$ = ${[A]}^{2}$

since magnitude of rate constant is same for all and concentration of reactant is greater than 1 and equal for all reactions from the rate law equation $γ_{1}$ < $γ_{2}$ < $γ_{3}$

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