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Q.

Ratio between longest wavelength of H atom in Lyman series to the shortest wavelength in Balmer series of He+  is

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a

365

b

43

c

59

d

14

answer is A.

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Detailed Solution

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Longest wavelength in Lyman Series of hydrogen atom arises from transition between n = 2 to n = 1 whose number is given by

v¯H21=  R×  121112122=34R

Shortest wavelength in Balmer series of He+ arises from transition between n =  to n = 2 whose wave number is given by

v¯He+2=  R×  2212212=RvHe+vH=λHλHe+       λHλHe+=4R3R=43

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