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Q.

Reactant A gives product B or C

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The possible reagents are:

(I) 2Na/liq.NH3

 (II) H2/Pd/CaCO3 (quinoline) 

 (III) 2H2/Pd/C

The correct statement with respect to the above conversion is/are:

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a

C is obtained on treatment with reagent (I)

b

C and B are obtained on treatment with reagent (II)

c

C is obtained on treatment with reagent (II)

d

B is obtained on treatment with reagent (I)

answer is C.

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Detailed Solution

Reagent (I) gives trans product. Reagents (II) and (III) give cis-product. The reagent I is called as Birch reagent and the intermediate is di anion and it is stable in trans form.

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