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Q.

Reaction -1:-  NaOH+H2O+P4 A  +  B        
Reaction -2:-  F2 +NaOHCold and diluteNaF+   C    +   D 
Reaction -3:-  Si  +  NaOH+H2O​​  E  +  F  


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Which of the following is/are correct?

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a

Reaction-2 is not disproportionation and bond angle of 'D' is greater than that of 'C' when both 'C' & 'D' are in gaseous phase

b

 Reaction -1 is disproportionation and hybridisation of central atom in B is sp3

c

Bonds of anion of 'Z' are stronger & shorter compared to that of anion of Y.

d

F is diamagnetic, and it reacts with the hardest alkali metal at 1073 K.

answer is B, C, D.

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Detailed Solution

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B  Is  PH3,  nohybridisation

C  is  OF2  D  is​  H2O,  Bond  angle  H2O>OF2

F  is  H2,    2Li+H21073K2LiH

Y  is  NaOCl      Z  is  NaClO3

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Reaction -1:-  NaOH+H2O+P4 →A  +  B  ↑      Reaction -2:-  F2 +NaOHCold and dilute→NaF+   C  ↑  +   D Reaction -3:-  Si  +  NaOH+H2O→​​  E  +  F  ↑Which of the following is/are correct?