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Q.

Reaction of one molecule of HBr with one molecule of 1, 3-butadiene at 40°C gives predominantly

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a

3-bromobutene under thermodynamically conrolled conditions

b

1-bromo-2-butene under thermodynamically controlled conditions

c

3-bromobutene under kinetically controlled conditions

d

1-bromo-2-butene under thermodynamically conrolled conditions

answer is D.

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Detailed Solution

At 40°C, thermodynamically controlled, 1, 4-addition product predominates.

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At low temperature (0 °C), kinetically controlled 1,2-addition product predominates.

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Reaction of one molecule of HBr with one molecule of 1, 3-butadiene at 40°C gives predominantly