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Q.

Read the following statements and choose the correct answer.                     

i. The boiling points of isomeric haloalkanes decreases with increase in branching

ii. The synthesis of alkyl flourides is best accomplished by swarts reaction

iii.The haloalkanes are more soluble in organic solvents

iv. The decreasing order of density among

CH2Cl2,CHCl3 and CCl4 is CH2Cl2>CHCl3>CCl4

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a

ii, iii and iv are correct

b

i, ii and iv are correct

c

i, ii and iii are correct

d

ii and iv are correct

answer is C.

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Detailed Solution

i, ii and iii are correct

More is the branching, less is the surface area, therefore less is the boiling point.

In Swarts' reaction, alkyl fluorides formed from alkyl chlorides or alkyl bromide in the presence of certain heavy metals having flourine.

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