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Q.

Read the following statements carefully. False statement among these statements is

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a

Pent – l–en–4–yne contains  10σ,3πbonds

b

All the carbon atoms of 1,3–butadiene are sp2 hybridized

c

Higher stability of CH33C+than  CH32CH+ cannot be explained by inductive effect

d

Paper chromatography is a Partition Chrmatograpy in which both stationary phase and mobile phase are liquids

answer is C.

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Detailed Solution

1..1                          2               3                   4          5  CH2=CHCH2CCH....   10σ,  3π

2.. sp2           sp2         sp2       sp2     CH2=CHCH=CH2

3..CH33C+ .......  9 H.C hydrogens and thee  +I groups(methyl gps); CH32C+H...... 6 H.C hydroges and two +I groups(methyl gps);

4…..Paper Chromatography …. Partition Chromatography not an adsorption chromatography

Mobile phase           ….. component to be detected (liquid)

Stationary phase ……… Water bound to cellulose (liquid)

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