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Q.

Read the passage given below and answer the following question:
A mixture of two aromatic compounds (A) and (B) was separated by dissolving in chloroform followed by extraction with aqueous KOH solution. The organic layer containing compound (A), when heated with alcoholic solution of KOH produce C7H5N (C) associated with unpleasant odour.

Question:

The reaction of (A) with alcoholic solution of KOH to produce (C) of unpleasant odour is called

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a

Ullmann reaction

b

Reimer-Tiemann reaction

c

Carbylamine reaction

d

Sandmeyer reaction

answer is B.

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Detailed Solution

Carbylamine reaction

C6H5NH2Aniline + CHCl3 + 3KOH (alc.)  C6H5NCPhenylisocyanide + 3KCI + 3H2O

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