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Q.

Read the passage given below and answer the following question:
A mixture of two aromatic compounds (A) and (B) was separated by dissolving in chloroform followed by extraction with aqueous KOH solution. The organic layer containing compound (A), when heated with alcoholic solution of KOH produce C7H5N (C) associated with unpleasant odour.

Question:

Direct nitration of an aromatic compound (A) is not feasible because

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a

The reaction cannot be stopped at the mononitration stage

b

 A mixture of o, m and p-nitroaniline is always obtained

c

Nitric acid oxidizes most of the aromatic compound to give oxidation products along with only a small amount of nitrated products

d

All of the above

answer is C.

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Detailed Solution

Direct nitration of aniline is not a feasible process because nitric acid oxidizes most of aniline to give oxidation products along with only a small amount of nitrated products.

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