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Q.

Reduction of hexose A (Molecular formula C6H12O6) with sodium borohydride gives compounds B and C. Compound B is optically inactive, where as compound C is optically active. Which of the following is compound A (D-psicose is C3-epimer of D-fructose, D-mannose is the C2-epimer of D-glucose)

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a

D-fructose

b

D-glucose

c

D-mannose

d

D-psicose

answer is D.

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Detailed Solution

Reduction of hexose A (Molecular formula C6H12O6) with sodium borohydride gives compounds B and CQuestion ImageD-psicose (D-psicose is C3-epimer of D-fructose, D-mannose is the C2-epimer of D-glucose).

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Reduction of hexose A (Molecular formula C6H12O6) with sodium borohydride gives compounds B and C. Compound B is optically inactive, where as compound C is optically active. Which of the following is compound A (D-psicose is C3-epimer of D-fructose, D-mannose is the C2-epimer of D-glucose)