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Q.

Reduction potentials of some ions are given below. Arrange them in decreasing order of oxidising power.

 Ion                         ClO4                       IO4                    BrO4Reduction              EΘ=1.19V           EΘ=1.65V       EΘ=1.74V potential EΘ/V            

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a

IO4>BrO4>ClO4

b

ClO4>IO4>BrO4

c

BrO4>ClO4>IO4

d

BrO4>IO4>ClO4

answer is A.

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Detailed Solution

Higher the reduction potential, higher is its tendency to get reduced. Hence, the order of oxidising power is:

ClO4>IO4>BrO4

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