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Q.

 Reduction potentials of Sn2+/Sn and Sn4+/Sn2+ are given below

Sn2++2eSn;       E0=0.14VSn4++2eSn2+;    E0=0.13V

On the basis of given data, select the correct statement (s).

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a

Sn4++Sn2Sn2+ is spontaneous 

b

Sn4+ is easily reduced to Sn

c

Sn2+ is stable and disproportionation reaction is not spontaneous

d

Sn2+ is unstable and disproportionates to Sn4+ and Sn

answer is B, D.

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For spontaneous reaction Ecell is positive and Gcell is negative

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 Reduction potentials of Sn2+/Sn and Sn4+/Sn2+ are given belowSn2++2e−⟶Sn;       E0=−0.14VSn4++2e−⟶Sn2+;    E0=0.13VOn the basis of given data, select the correct statement (s).