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Q.

Regarding H2O2 and O3 the correct statements are

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a

Both are unstable but O3 is less stable than hydrogen peroxide

b

O – O bond length is shorter in O3 than in  H2O2

c

Heat of formation of  H2O2 is exothermic while the heat of formation of O3 is endothermic

d

Both are polar but the dipolemoment of ozone is greater than hydrogen peroxide 

answer is A, B, C.

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Detailed Solution

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O–O bond order is 1.5 in ozone which is more than the O–O bond order 1 in H2O2. Ozone is endothermic substance while the formation of H2O2 is exothermic heat of formation of H2O2  liquid is 187.78kJmol1 and that of O3 is +142.7kJmol1.  So ozone is less stable than H2O2.  Dipolemoment of H2O2 is 2.1 D and that of ozone is 0.53 D.

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