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Q.

Regarding monohalides of oxygen family, correct statements are

A) They exist as dimers.

B) They have non-planar, non-linear, open book structure.

C) They undergo disproportionation.

D) They do not contain any non-polar bonds.

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a

A,B,C only

b

A,B,C,D

c

A,B only

d

A,C,D only

answer is C.

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Detailed Solution

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Mono halides like S2Cl2 , Se2Cl2 exist as dimers.

Question Image

Non-linear , non-planar open book structure

2\mathop {S{e_2}}\limits^{ + 1} C{l_2} \to \mathop {Se}\limits^{ + 4} C{l_4} + 3\mathop {Se}\limits^0

Se-Se bond is non-polar

Se-Cl  bond is polar

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