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Q.

Regarding phosphorous pentachloride, the incorrect statement is

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a

In liquid phase it exists as an ionic solid

b

In solid state it exists as PCl4+PCl6-

c

In gas phase , it has trigonal bipyramidal geometry

d

P-Claxial bond length is longer than  P-Clequatorial bond length in gas phase

answer is D.

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Detailed Solution

In both gas phase and liquid phase it exists as a monomer;

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