Q.

Regarding the liquid mixture of 68% nitric acid + 32% water by mass, incorrect statement is

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a

Vmixing=-ve

b

Hmixing=-ve

c

Boiling point is lesser than 373 K

d

It shows negative deviations from Raoult's law

answer is A.

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Detailed Solution

Azeotropic mixture is a constant boiling mixture.

At certain concentration, both liquids boil at same temperature.

It is not possible to separate them by fractional distillation.

68% nitric acid + 32% water is a maximum boiling azeotrope.

Maximum boiling Azeotrope means higher boiling point than any of the two components ( > 373 K );

Lesser vapour pressure than expected from Raoult's law ;

A-B interactions are stronger than A-A and B-B interactions ;

Attractions dominate;

It shows negative deviations from Raoult's law

Hmix=-ve ; Vmix=-ve ; Gmix=-ve ; Smix=+ve ;

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