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Q.

Regarding the liquid mixture of 68% nitric acid and 32% water by mass, incorrect statement is

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a

Boiling point is lesser than 373 K

b

It shows negative deviation from Raoult’s law

c

ΔHmixing=Ve

d

ΔVmixing=Ve

answer is A.

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Detailed Solution

68% HNO3+32% water is a Azeotropic mixture (maximum boiling Azeotropic mixture) 
  this mixture shows negative deviation from Raoults law.

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