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Q.

Regarding the reaction of NaHSO3 with carbonyl compounds, the correct statement is

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a

Aldehyde sodium bisulphite derivatives are crystalline in nature

b

Equilibrium will be towards left in its reaction with aldehydes

c

It reacts with all carbonyl compounds

d

Equilibrium will be towards right in its reaction with ketones

answer is D.

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Detailed Solution

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1) Cannot react with methyl ketones and aromatic ketones.
2) Aldehyde + NaHSO3, equilibrium is towards right
3) Ketone + NaHSO3, equilibrium is towards left

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