Regarding the reaction of ${NaHSO}_{3}$ with carbonyl compounds, the correct statement is

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It reacts with all carbonyl compounds

Equilibrium will be towards left in its reaction with aldehydes

Equilibrium will be towards right in its reaction with ketones

Aldehyde sodium bisulphite derivatives are crystalline in nature

answer is D.

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Detailed Solution

1) Cannot react with methyl ketones and aromatic ketones.
2) Aldehyde + NaHSO₃, equilibrium is towards right
3) Ketone + NaHSO₃, equilibrium is towards left

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