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Replacement of Cl of chlorobenzene to give phenol requires drastic conditions but chlorine of 2, 4-dinitrochlorobenzene is readily replaced. This is because

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An Intiative by Sri Chaitanya

NO₂makes the ring electron rich at ortho and para positions

NO₂withdraws e^-from meta-position

NO₂donates e^- at m-position

NO₂withdraws e- from ortho/para-positions

answer is D.

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Detailed Solution

-NO₂group withdraws electrons from o- and p-positions and hence activates the —Cl present on that position towards nucleophilic substitution.

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