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Replacement of of chlorobenzene to give phenol requires drastic conditions but chlorine of 2,4-Dinitrochlorobenzene is readily replaced. This is because

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NO₂ makes the ring electron rich at ortho and para positions

NO₂ withdraws e^- from meta position

NO₂ donates e^- at m-position

NO₂ withdraws e^- from ortho/para- positions

answer is D.

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Detailed Solution

NO₂ group withdraws electrons from o-and p- positions and hence activates the -Cl present on that position towards nucleophilic substitution. C-Cl bond weakens.

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