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Q.

Resistance of a conductivity cell (cell constant 129 m1 ) filled with 74.5 ppm solution of KCl is 100 Ω (labelled as solution 1). When the same cell is filled with KCl solution of 149 ppm, the resistance is 50 Ω (labelled as solution 2). The ratio of molar conductivity of solution 1 and solution 2 is i.e. 12=x×103. The value of x is ___________. (Nearest integer) Given, molar mass of KCl is 74.5 gmol1.

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Detailed Solution

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lA=129m1

KCl solution 1: 74.5 ppm,R1=100Ω

KCl solution 2: 149ppm, R2=50Ω

Here, ppm1ppm2=m1M2(=W1MoV×VW2m0)

12=k1×1000M1k2×1000M2=k1k2×M2M1=50100×2=12=1,000×103

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