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Q.

Resistance of a conductivity cell filled with a solution of an electrolyte of concentration 0.1 M is 100Ω The conductivity of this solution is 1.29 S m-1 . Resistance of the same cell when filled with 0.2 M of the same solution is 520 Ω. The molar conductivity of 0.02 M solution of the electrolyte will be

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a

 1240 × 10-4 S m2 mol-1

b

 12.4× 10-4 S m2 mol-1

c

 124×10-4 S m2 mol-1

d

 1.24 × 10-4 S m2 mol-1

answer is B.

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Detailed Solution

Given R=100 Ω and κ=1.29 S m1

Cell constant Kcell=κR=1.29 S m1(100 Ω)=129 m1

For 0.02 M solution, we have κ=KR=129m1520Ω and Λ=κc=(129/520) S m10.02×103 mol m3=124×104 Sm2 mol1

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