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Q.

Resistance of the conductivity of a cell filled with 0.1 M KCl solution is 100Ω. If the resistance of the same cell when filled with the 0.02 M KCl solution is 520Ω. Then the molar conductivity of 0.02 M KCl solution will be [The conductivity of 0.1 M KCl solution is 1.29 S.m–1]

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a

124 S cm2 mole–1

b

1.24 S.m2  mole–1

c

124 S.m2  mole–1

d

1.24 S.cm2  mole–1

answer is C.

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Detailed Solution

For 0.1 M KCl
K=1RGx 1.29=Gx100Gx=129m1 or 1.29cm1ΛM=1000×kM=1000×1.29520×2×102
=124 S.cm2  mole–1

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Resistance of the conductivity of a cell filled with 0.1 M KCl solution is 100Ω. If the resistance of the same cell when filled with the 0.02 M KCl solution is 520Ω. Then the molar conductivity of 0.02 M KCl solution will be [The conductivity of 0.1 M KCl solution is 1.29 S.m–1]