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Q.

(S)-2-chloropentane undergoes nucleophilic substitution when treated with 1.5 M
NaOH solution, reaction follows the given rate law:
Rate = 2.35 x 10-5[R - X ][-OH] + 5.40 x 10-6[R - X ]
Calculate percentage of retention product in product mixture.(Report in nearest integer)

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answer is 7.

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Detailed Solution

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%SN1=5.4×10−6(R−X)(3.525+0.54)10−5Rx×100=0.544.065×100=13.28% racemisation % retention =13.282=6.64≈7

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