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Q.

S.R.P values of some electrodes are given below. 

EMg+2/Mgo=-2.37 V ; E12Cl2/Cl-o=+1.36 V ; EAg+/Ago=+0.8 V ; EZn+2/Zno=-0.76 V ;  

From the above data, identify the best reducing agent

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a

Zn

b

Mg

c

Cl2

d

Ag

answer is B.

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Detailed Solution

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From the values of S.R.P

Tendency to undergo reduction ….  Cl2 > Ag+ > Zn+2> Mg+2

                      Oxidizing power …..   Cl2 > Ag+ > Zn+2> Mg+2

                     Reducing power ….. Mg > Zn > Ag > Cl-

Electrode with lower SRP value readily undergoes reduction

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