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Q.

S1  : Among K+ , Mg2+ and Al3+ ions Al3+is the smallest one.

S2 : The negative value of electron gain enthalpy of Cl>F because there is weak electron-electron repulsion in the bigger 3p-sub shell of Cl as compared to compact 2psubshell of F.

S3 :Formation of S2- and Ar- ,both require the absorption of energy

S4 : The following set of elements represent the incorrect order of magnitude of electron gain enthalpy values  S>O

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a

FTTF

b

TTTF

c

TTTT

d

FFTT

answer is C.

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Detailed Solution

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  • for isoelectronic species, greater the positive charge lesser will be its size 
  • second period elements will have low electron affinity than that of third period elements
  • for noble gases even adding first electron is endothermic

       *   sulphur electron affinity is more than oxygen is correct not incorrect, 

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