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Q.

S2O3-2H+SO4-2. Equivalent weight of S2O3-2 ( M = Molar mass)

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a

M

b

M4

c

M2

d

M8

answer is B.

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Detailed Solution

O.S of sulphur atom in thiosulphate ion and sulphate ion is +2 and +6 respectively.

n-factor = 2(6-2) = 8 ;

Alternatively 

O.states of two sulphur atoms in thiosulphate ion are -2 and +6 whereas in sulphate ions both sulphur atoms have +6 state.

Thus change in O.S is -2+6 …change in O.S = 8 ;

n - factor = 8

Eq.wt =M8

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S2O3-2→H+SO4-2. Equivalent weight of S2O3-2 ( M = Molar mass)