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Q.

Salt solution[X]Salt solutiondil. HCl[Y]White ppt

                                                              

           If ppt.is washed by decantation and dilute is added 

                                                 White ppt.(Z)

Here, white ppt. of ['Y'] is

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a

Hg2Cl2

b

PbCl2

c

AgCl

d

Pb(OH)2

answer is A.

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Detailed Solution

By adding a solution containing chloride ions to a solution of lead(II) nitrate, white precipitate lead(II) chloride can be produced. You might use sodium chloride solution to give the chloride ions, but it is typically quicker to simply add some weak hydrochloric acid.

Pb2+(aq)+2Cl(aq)PbCl2(s)

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