Q.

Sandmeyer's reaction cannot be used in the preparation of

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a

C6H5I

b

C6H5Cl

c

C6H5Br

d

C6H5CN

answer is A.

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Detailed Solution

C6H5-N2+Cl-Cu2Cl2/HClC6H5Cl ; C6H5-N2+Cl-Cu2Br2/HBrC6H5Br ; C6H5-N2+Cl-Cu2CN2/KCNC6H5CN; The above reactions are examples of sandmeyer's reaction  but the reaction below is not. C6H5-N2+Cl-KIC6H5I ; 

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Sandmeyer's reaction cannot be used in the preparation of