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Q.

Select correct code about complex CrNO2NH35ZnCl4.

(P) IUPAC name of the compound is Pentaammine Nitrito-N-chromium (ill) tetrachloridozincate (II)

(Q) It shows geometrical isomerism 

(R) It shows linkage isomerism 

(S) It shows co-ordination isomerism

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a

R, S only

b

P, R and S only 

c

Q, R, Sonly 

d

P, Q, R and S

answer is B.

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Detailed Solution

Pentaammine Nitrito-N-chromium (III) tetrachlorozincate is the IUPAC name for the compound [Cr (NO) (II). N denotes that the nitro group is connected to the metal atom via the N atom.

Because nitro ligand is an ambidentate ligand with two donor atoms, linkage isomerism is possible.

It possesses coordination isomers. The coordination isomers are as follows:

CrClNH35ZnCl3NO2,CrCl2NH34ZnCl2NO2NH3 and [ZnNO2NH3].

So, option B is correct answer.

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