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Q.

Select incorrect statement?

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a

Heat of vapourisation for a pure solvent and for a dilute solution are similar 

b

Entropy change between solution and vapour is smaller than the entropy change between pure solvent and vapour

c

Boiling point of the solution is larger than that of the pure solvent

d

vapour pressure of solvent is always lower than vapour pressure of solution

answer is D.

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Detailed Solution

HVapsolution HVapSolvent 

[Because similar intermolecular forces are involved in both cases]

TbSolvent>TbSolution SVapSolution<SVapSolvent

v.p of solvent will always be higher than solution containing non volatile solute

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