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Q.

Select incorrect trend for extent of hydrolysis :

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a

SF4>SF6

b

NCl3>NF3

c

PF3>PCl3

d

SeF6>SF6

answer is C.

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Detailed Solution

The proper trend is PF3 >PCl3, hence PF3 >PCl3 is erroneous. PF3 is more quickly hydrolyzed than PCl3 because it is less stable and has a weaker P-F bond.

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