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Q.

Select molecule(s) in which all P-Cl lengths are identical.

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a

PCl3F2

b

PCl3

c

PCl2F3

d

PCl4F

answer is A, B, C.

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Detailed Solution

The molecule(s) in which all P-Cl lengths are identical is P Cl subscript 3 F subscript 2 P Cl subscript 3 P Cl subscript 2 F subscript 3 because axial bond length is shorter than the equatorial bond length.

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