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Q.

Select pair of compounds in which both have different hybridisation but have same molecular geometry.

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a

ICI2,BeCl2

b

BF3,BrF3

c

BCl3,PCl3

d

PCl3,NCl3

answer is B.

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Detailed Solution

Both ICl2 and BeCl2 are linear but ICl2 has sp3d and BeCl2 has sp hybridization. ICl2 has a structure with 5 electron pairs. Its hybridization is hence sp3d. The linear structure is due to the fact that of those 5 electron pairs, 2 are bond pairs and 3 are lone pairs. As BeCl2 Its structure is linear and contains sp hybridization.

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