Q.

Select reagent(s) which is/are used in laboratory t-0 differentiate 1°, 2° and 3° amines from each other:

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a

CS2,HgCl2

b

NaNO2,HCl

c

PhSO2Cl

d

CHCl3,KOH

answer is A, C.

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Detailed Solution

(a) 1HClNaNO2 R-OH C.A.N. > (Red Colour)

2HClNaNO2 RNN=O (Oily liquid) 

3HClNaNO2  Salt 

(b) Hinsberg's test can distinguish 1°, 2° and 3° amines.

(c) Carbylamine test is given by only 1° amines. 

(d) Mustard oil reaction is also given by 1° amine only.

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