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Q.

Select the complex compound which show geometrical as well as optical isomerism.

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a

CrH2O4NH323+

b

Ni(en)32+

c

CoBrCl(en)2+

d

 [Zn(gly) 2 ] 

answer is C.

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Detailed Solution

Ma4b2n± shows geometrical isomerism but not optical isomerism.
M(AA)3n± shows optical isomerism but not geometrical isomerism.
M(AA)2bcn± shows geometrical as well as optical isomerism.

 

Question Image

M(AB)2n± (tetrahedral complex) (optically active) 

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