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Q.

 Select the correct code about complex CrNO2NH35ZnCl4 : 
(I) IUPAC name of compound is pentaamminenitrito-N-chromium (III) tetrachlorozincate(Il)
(II) It shows geometrical isomerism
(III) It shows linkage isomerism
(IV) It shows coordination isomerism

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a

III, IV

b

I, III and IV

c

II, III and IV

d

I, Il, III and IV

answer is B.

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Detailed Solution

(I) IUJPAC name is Pentaamminenitrito-N-chromium(Ill) tetrachlorozincate (II)
(II) It does not exhibit geometrical isomerism
 (III) It shows linkage isomerism due to presence of ambidentate ligand NO2
 (IV) Its coordination isomers are : 
CrClNH35ZnCl3NO2 CrCl2NH34ZnCl2NO2NH3ZnNO2NH33CrCl4NH32

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