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Q.

Select the correct order.

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a

${LiNO}_{3} > {NaNO}_{3}$ (Thermal stability)

b

$LiNO 3 < NaNO 3$ (Thermal stability)

c

$AgCl > KCl$ (Covalent character) $(r_{{Ag}^{+}} = r_{K^{+}})$

d

$AgCl < KCI$ (Covalent character)

answer is B.

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Detailed Solution

Thermal stability is directly proportional to the ionic character. Thus. thermal stability order is given as,

$LiNO 3 < NaNO 3$

Greater the cation size lesser the covalent character.

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