Q.

Select the correct statement about the following chemical species :

O2,O2+,N2,NO,H2+,H2

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a

The bond length of O2+ is shorter than O2 due to removal of electron from π*

b

H2+is more stable than H2 although both have same bond order

c

Magnetic moment of NO is greater than O2

d

The ionisation energy of N2 is greater than N

answer is B, C, D.

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Detailed Solution

(a) NO has 1 unpaired electron while O2 has 2 .

(c) The first ionization energy of N2 is more than the first ionization energy of atomic nitrogen as the energy of bonding molecular orbitals of nitrogen molecule are lower than the atomic orbital of nitrogen atom.
(d)H2+is more stable because it has less number of antibonding electron.

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