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Q.

Select the correct statement about N2F4 and N2H4.

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a

In N2F4 d-orbitals are contracted by electronegative F-atoms but d-orbital contraction is not possible by H atom in N2H4.

b

NN bond energy in N2F4 is greater than NN bond energy in N2H4.

c

HN^H bond angle in N2H4 is less than FN^F angle of N2F4.

d

The NN bond length in N2F4 is more than that in N2H4

answer is D.

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Detailed Solution

NN bond in N2F4 has greater  % s-character than in N2H4.

So, the correct answer is NN bond energy in N2F4 is greater than NN bond energy in N2H4.
Hence, the correct answer is D.

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