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Q.

Select the correct statement for the following molecules.

(P) PF2CH33    (Q) PF2CF33

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a

Both have trigonal bipyramidal structure.

b

Both have same dipole moment.

c

P-F bond length is longer in PF2(CH3)3 than the PF2(CF3)3.

d

P-F bond length is smaller in PF2(CH3)33 than the PF2(CF3)3.

answer is A, B, C.

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Detailed Solution

The structure,

Question Image

 

x>y because -CF3 has greater -I than -CH3 group.
So, e correct statement for the PF2CH33 and PF2CF33 molecules are,

a) Both have trigonal bipyramidal structure .

b) Both have same dipole moment.
c) P-F bond length is longer in PF2(CH3)3 than the PF2(CF3)3.

Hence, the correct option is a,b,c.

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