Q.

Select the correct statement regarding B2H6

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a

It has only 2c2e bond

b

It is planar 

c

It does not react with NH3

d

Hybridisation of boron is sp3

answer is D.

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Detailed Solution

Boron contains three valence electrons, thus when it undergoes hybridization, it should form three bonds in a molecule (sp2) since only the s and p orbitals are utilised, and the final p orbital is left empty.

However, the diborane,B2H6 , has three centred bonds and two electrons per bond. Four hydrogen atoms form a connection with each boron atom. Tetrahedral geometry results from this.

Thus, each boron atom has undergone sp3 hybridization.

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