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Q.

Select the CORRECT statement (s).

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a

In the manufacture of H2O2 by electrolysis a mixture of conc. H2SO4  and (NH4)2SO4  is used as electrolyte,  H2O2 is formed at anode and  H2 is liberated at cathode.

b

Oxidation state of sulphur in Marshall’s acid and caro’s acid is same. 

c

Peroxides and super oxides on treatment with ice cold dilute acid give H2O2

d

In butterfly structure of CrO5, there are two peroxy bonds. 

answer is B, C, D.

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Detailed Solution

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H2SO5  Caro’s acid  +6
 H2S2O8  Marshall’s acid +6
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