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Q.

Select the correct statement(s).

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a

m of strong as well as weak electrolytes can be obtained by extrapolation of graph between m and ctoc0

b

m (molar conductance at infinite dilution) of strong electrolytes as well as weak electrolytes can be obtained by Kohlraush’s law m=x+λ++yλ for  AxBy

c

AgCl can be obtained by known value of  AgNO3,HCl  andHNO3

d

m(BaSO4)=m(BaCl2)+m(H2SO4)2m(HCl)

answer is B, C, D.

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Detailed Solution

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For strong electrolyte, variation in graph is uniform, hence m  can be extrapolated to C0, to obtain  m
In case of weak electrolyte, variation of m  with C is rapid in lower concentration range (higher dilution) hence graph is not uniform and  m cannot be obtained by extrapolation to  C0. Thus (a) is incorrect 

Al2(SO4)=2Al3++3SO42
m=2λAl++3λSO42

Thus (a) is true
C) Also  BaSO4=BaCl2+H2SO42HCl
Thus, it is also correct based on Kohlrausch’s Law
d)  AgCl=AgNO3+HClHNO3=Ag++cl
Thus, correct based on Kohlrausch’s law

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