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Q.

Select the correct statement(s).

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a

In group Ill, Fe3+ and Cr3+ can be differentiated by increasing NH4+ ion concentration.

b

In Vth group, Na2CO3 is added to precipitate out only the carbonates of Ba2+, Sr2+and Ca2+  

c

Like brown ring · test, diphenylamine test is given only by salts containing NO3.

d

Sodium chloride on heating with .aqueous solution of K2Cr2O7 and concentrated H2SO4 produces deep red vapours.

answer is A.

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Detailed Solution

NH4+ ions are increased to suppress release of OH– ions, hence  is . Colour of precipitate is different.

By increasing NH4+ ions the discharge of oh- ion is inhibited. Hence, Fe(OH)3 attained the solubility  product.

Hence, the correct option is A.

 

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