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Q.

Select the correct statement(s)

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a

The rate law of the elementary reaction 2A→B + C; must be Rate = K [A]2

b

The rate law for the complex reactionA + B→C, might not be Rate = K[A][B]

c

If the partial orders differ from the coefficients in the balanced reaction, the reaction must be complex.

d

If the partial orders equal to corresponding coefficients in the balanced reaction, the reaction must be elementary

answer is A.

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Detailed Solution

The rate law of elementary reaction 2 A → B + C

(i) According to law of mass action rate = K[A]2 Order = 2

(ii) The rate law for the complex reaction

A + B → Cmight not be rate = K[A][B]

Complex reaction are depends on mechanisms

Based on mechanism find out the slow step if the partial orders differ from the co-efficient in the balanced reaction the reaction must be complex.

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