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Q.

Select the correct statements:

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a

"Spitting of silver" can be prevented by covering the surface of molten Ag with charcoal.

b

An alloy is a blend of metals prepared by mixing the compounds

c

The melting and boiling points of Zn, Cd and Hg are high.

d

Order of paramagnetic character is: Cr > Fe > Zn

answer is B, C, .

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Detailed Solution

 (1) On heating molten Ag, it absorbs oxygen which is again released  on cooling is called "spitting of Ag" and isprevented by

charcoal 

(2) Cr  3d5 4s1 (6 unpaired e-,s), Fe3d64s24 unpaired ers
Zn3d104s2 (no unpaired e5s
(3) Fact
(4) M. Pt. and B. Pt., are low.
In Zn, Cd and Hg, (n - 1)d orbitals are filled to their maximum capacity. These e-'s do not take part in bonding. Thus, metallic bonding is weak and hence low M. Pt. and B. Pt.

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