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Q.

Select the correct statements:

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a

For CsCl unit cell (edge-length =a ), rc+ra=32a, rc= radius of cation, ra= radius of anion 

b

For NaCl unit cell (edge-length =l ), rc+ra=l2  

c

The void space in bcc unit cell is 0.68

d

The void space % in a face centred unit cell is 26%

answer is A, B, D.

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Detailed Solution

In bec structure, r++r=32a

Hence, for CsCl,rc+ra=32a

(A) is correct.

Since, NaCl crystallizes in fce structure

2rc+2ra=edge length of the unit cell

Hence, rc+rb=12

(B) is correct.

Since packing fraction of a bec unit cell is 0.68

 Void space =1-0.68=0.32

(C) is not correct.

In fce unit ceil, PF=74%

VF=10074=26%

(D) is correct.

Hence, (A),(B) and (D) are the correct answers.

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