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Q.

Select the correct statement(s) about the compound NO[BF4]

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a

It has 5σ and 2π bond

b

B-F bond length in this compound in lower than in BF3

c

It is a diamagnetic species

d

Nitrogen - oxygen bond length is higher than in nitric oxide (NO)

answer is A, C.

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Detailed Solution

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Total σ- bonds = 5 - Diamagnetic
Total π- bonds = 2- Bond order of NO+ is 3 > NO

B−F bonds are longer in BF4-​ than in BF3​ due to absence of pπ−pπ back bonding in BF4-.

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